This Topical Collection of Molecules provides the most recent advancements and trends within the framework of food analysis, confirming the growing public, academic, and industrial interest in this field. The articles broach topics related to sample preparation, separation science, spectroscopic techniques, sensors and biosensors, as well as investigations dealing with the characterization of macronutrients, micronutrients, and other biomolecules. It offers the latest updates regarding alternative food sources (e.g., algae), functional foods, effects of processing, chiral or achiral bioactive compounds, contaminants, and every topic related to food science that is appealing to readers. Nowadays, the increasing awareness of the close relation among diet, health, and social development is stimulating demands for high levels of quality and safety in agro-food production, as well as new studies to fill gaps in the actual body of knowledge about food composition. For these reasons, modern research in food science and human nutrition is moving from classical methodologies to advanced instrumental platforms for comprehensive characterization. Nondestructive spectroscopic and imaging technologies are also proposed for food process monitoring and quality control in real time.

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Nowadays, we are witnessing highly dynamic research activities related to the intriguing field of biodegradable materials with plastic-like properties. These activities are stimulated by the strengthened public awareness of prevailing ecological issues connected to growing piles of plastic waste and increasing greenhouse gas emissions; this goes hand-in-hand with the ongoing depletion of fossil feedstocks, which are traditionally used to produce full carbon backbone polymers. Polyhydroxyalkanoate (PHA) biopolyesters, a family of plastic-like materials with versatile material properties, are increasing considered to be a future-oriented solution for diminishing these concerns. PHA production is based on renewable resources and occurs in a bio-mediated fashion through the action of living organisms. If accomplished in an optimized way, PHA production and the entire PHA lifecycle are embedded into nature´s closed cycles of carbon. Sustainable and efficient PHA production requires understanding and improvement of all the individual process steps. Holistic improvement of PHA production, applicable on an industrially relevant scale, calls for, inter alia, consolidated knowledge about the enzymatic and genetic particularities of PHA-accumulating organisms, an in-depth understanding of the kinetics of the bioprocess, the selection of appropriate inexpensive fermentation feedstocks, tailoring of PHA composition at the level of its monomeric constituents, optimized biotechnological engineering, and novel strategies for PHA recovery from biomass characterized by low energy and chemical requirements. This Special Issue represents a comprehensive compilation of articles in which these individual aspects have been addressed by globally recognized experts.

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"Advances in Sustainable Polymeric Materials" is a compilation of 22 articles highlighting the recent progress in the research and development of polymeric materials, with an emphasis on sustainability. Some papers focus on developing biodegradable plastics obtained from renewable sources such as starch and biomass waste. Other articles discuss modification techniques to improve the mechanical properties of biopolymers such as PLA and PHAs. The use of recycled polymeric materials in the construction industry is highlighted as a low-cost and environmentally friendly solution.Other studies include investigations on polymer-modified bitumen, a novel sound-absorbing material made from used palm-oil-based polyurethane foam and water hyacinth fibre composite, bio-based epoxy-lignin coatings, TiO2 nanocomposites, the photocatalytic activity of different polymeric composites, sustainable elastomers, interactions between vanillyl-alcohol-based epoxy and cross-linkers, polyvinyl chloride sorbent for rare earth elements, lignin-based thermoplastic, the chemical foaming process of polylactic acid, microencapsulation strategies for essential oils, electrochemical sensors for glucose determination, and an intelligent drug delivery system based on pH-sensitive polymeric formulations.It is important to recognize that the field of sustainable polymeric materials is vast and rapidly evolving, and while a single volume cannot entirely capture all the developments occurring in this field, this collection provides readers with a valuable introduction and overview of the topic.

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This reprint, "Advances in Sustainable Polymeric Materials II”, contains 16 studies and further cutting-edge research that illustrate how these challenges can be addressed through the use of advanced materials, sustainable polymers, and green technologies. It highlights the importance of efficient catalysts, bio-based materials, and green chemical processes and demonstrates how cellulose derivatives and other natural materials can be integrated into polymer compositions. The reprint also explores the use of electrospun membranes and reactive eutectic solvents for greener methods of wastewater treatment and material synthesis, and the potential of agri-food waste and biomaterials for fully bio-based polymer coatings and materials. It also discusses the stabilization and preservation of natural extracts and active ingredients, showcasing the importance of encapsulation and nanotechnology in preserving these substances' beneficial properties. Each chapter provides detailed insight into how natural resources can be harnessed to create high-performance products while maintaining a strong commitment to environmental protection. These innovations not only improve the performance of materials but also contribute to reducing the ecological footprint of industrial processes.

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This reprint focuses on studies dealing with bio-based materials and its contribution to a circular economy. Research dealing with recycling, waste conversion to bio-based products, the development of bio-based composites, and surface treatments on cellulose fibres have been included in this reprint.

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Block copolymers with crystallizable blocks have moved into the focus of current research, owing to their unique self-assembly behaviour and properties. New synthetic concepts give, for example, even access to tetrablock copolymers with four crystalline blocks, bio-based thermoplastic elastomers (e.g., based on ABA triblock copolymers with poly(L-lactide) (PLLA) hard segments), and allow new, exciting insights into the interplay of microphase separation and crystallization in controlling self-assembly in bulk (confined vs. break-out crystalliza­tion).Concerning self-assembly in solution, crystallization-driven self-assembly (CDSA) paved the way to a myriad of crystalline-core micellar structures and hierarchical super­structures that were not accessible before via self-assembly of fully amorphous block copolymers. This allows for the production of cylindrical micelles with defined lengths, length distribution, and corona chemistries (block type or patchy corona), as well as branched micelles and fascinating micellar superstructures (e.g., 2D lenticular platelets, scarf-shaped micelles, multidimensional micellar assemblies, and cross and “windmill”-like supermicelles).This Special Issue brings together new developments in the synthesis and self-assembly of block copolymers with crystallizable blocks and also addresses emerging applications for these exciting materials. It includes two reviews on CDSA and eight contributions spanning from membranes for gas separation to self-assembly in bulk and solution.

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Continuous research advances have been observed in the field of environmentally-friendly polymers and polymer composites due to the dependence of polymers on fossil fuels and the sustainability issues related to plastic wastes. This book compiles the most recent research works in biopolymers, their blends and composites, and the use of natural additives, such as vegetable oils and other renewable and waste-derived liquids, with their marked environmental efficiency devoted to developing novel sustainable materials. Therefore, Environmentally Friendly Polymers and Polymer Composites provides an overview to scientists of the potential of these environmentally friendly materials and helps engineers to apply these new materials for industrial purposes.

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Beauty masks, diapers, wound dressings, wipes, protective clothes and biomedical products: all these high-value and/or large-volume products must be highly compatible with human skin and they should have specific functional properties, such as anti-microbial, anti-inflammatory and anti-oxidant properties. They are currently partially or totally produced using fossil-based sources, with evident issues linked to their end of life, as their waste generates an increasing environmental concern. On the contrary, biopolymers and active biomolecules from biobased sources could be used to produce new materials that are highly compatible with the skin and also biodegradable. The final products can be obtained by exploiting safe and smart nanotechnologies such as the extrusion of bionanocomposites and electrospinning/electrospray, as well as innovative surface modification and control methodologies. For all these reasons, recently, many researchers, such as those involved in the European POLYBIOSKIN project activities, have been working in the field of biomaterials with anti-microbial, anti-inflammatory and anti-oxidant properties, as well as biobased materials which are renewable and biodegradable. The present book gathered research and review papers dedicated to materials and technologies for high-performance products where the attention paid to health and environmental impact is efficiently integrated, considering both the skin-compatibility of the selected materials and their source/end of life.

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This book collects the articles published in the Special Issue “Polymeric Materials: Surfaces, Interfaces and Bioapplications”. It shows the advances in polymeric materials, which have tremendous applications in agricultural films, food packaging, dental restoration, antimicrobial systems, and tissue engineering. These polymeric materials are presented as films, coatings, particles, fibers, hydrogels, or networks. The potential to modify and modulate their surfaces or their content by different techniques, such as click chemistry, ozonation, breath figures, wrinkle formation, or electrospray, are also explained, taking into account the relationship between the structure and properties in the final application. Moreover, new trends in the development of such materials are presented, using more environmental friendly and safe methods, which, at the same time, have a high impact on our society.

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The aim of this reprint devoted to the topic “Polymers and the Environment” was to pursue environmentally friendly objectives for polymer-based materials under a two-fold perspective, applied and academic. In the 1980s, the first global environmental crisis occurred with an emphasis on the role of plastics in big cities’ massive solid waste streams. It was apparent then (and now) that the best environmental management practices required solid scientific and technical knowledge. Moreover, once at the end of their useful life, these plastics become involved in their materials (polymers and additives) into a circular economy strategy conjugated with the non-steady scenarios of the other key sectors of the economy, industry, society, and policy. Thus, linking tandem polymers and the environment has led, 40 years later, to a wide polymer research field devoted to continuously improving the environmental performance of polymer and polymer-based materials. This strategy comprises all the steps in the polymer management chain, from the raw materials to the polymers, many of which come from classical and renewable sources (the so-called bioplastics). Additionally, there is a need to improve the processability, ultimate properties, and performance by employing friendly environment additives; the recyclability of the materials; and the development of innovative and disruptive processes allowing better mechanical and energy recovery, including chemical recycling. This reprint includes approaches related to this frontrunner polymer science and technology area.

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The combination of functional polymers with inorganic nanostructured compounds has become a major area of research and technological development owing to the remarkable properties and multifunctionalities deriving from their nano and hybrid structures. In this context, polyhedral oligomeric silsesquioxanes (POSSs) have increasing importance and a dominant position with respect to the reinforcement of polymeric materials. Although POSSs were first described in 1946 by Scott, these materials, however, have not immediately been successful if we consider that, starting from 1946 and up to 1995, we find in the literature 85 manuscripts regarding POSSs; which means that less than two papers per year were published over 50 years. Since 1995, we observe an exponential growth of scientific manuscripts concerning POSSs. It is changing from an annual average of 20 manuscripts for the period 1995–2000 to an annual average of about 400 manuscripts, with an increase of 2800%. The introduction of POSSs inorganic nanostructures into polymers gives rise to polymer nanostructured materials (PNMs) with interesting mechanical and physical properties, thus representing a radical alternative to the traditional filled polymers or polymer compositions.

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