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Properties and Reactions of Transition Metals and Transition Metal Complexes in Ionic Liquids
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In this thesis, studies involving ionic liquids (ILs) in the context of IL-transition metal reactions were reported on: the thermochromatic transformation of a cobalt thiocyanate-containing IL, the characterisation of polyhalide ionic liquids, the corrosion of group 11 metals by trihalide ILs, and the comproportionation of copper metal and CuII salts in solution. X-ray photoelectron spectroscopy (XPS) was the main technique used in all of these studies, but other techniques such as mass spectrometry (MS) and scanning electron microscopy (SEM) were also used.
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