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The Effects of Internal Stress and Lithium Transport on Fracture in Storage Materials in Lithium-Ion Batteries
Klinsmann, Markus
2016
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Fracture of storage particles is considered to be one of the major reasons for capacity fade and increasing power loss in Li-ion batteries. In this work, we tackle the problem by merging a coupled model of mechanical stress and diffusion of Li-ions with a phase field description of an evolving crack. The novel approach allows us to study the evolution of the Li concentration together with the initiation and growth of a crack in an arbitrary geometry and without presuming a specific crack path.
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Keywords
- Li-Diffusion
- Li-Ion-Batteries
- Lithium-Diffusion
- Lithium-Ionen-BatterienCrack Growth
- Phasefield
- Phasenfeld
- Risswachstum
- Speicherpartikel
- Storage Particles