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Electrochemical Surface Science: Basics and Applications
Gaetano Granozzi and Nicolas Alonso-Vante
2019
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Electrochemical surface science (EC-SS) is the natural advancement of traditional surface science (where gas–vacuum/solid interfaces are studied) to liquid (solution)/electrified solid interfaces. Such a merging between two different disciplines—i.e., surface science (SS) and electrochemistry—officially advanced ca. three decades ago. The main characteristic of EC-SS versus electrochemistry is the reductionist approach undertaken, inherited from SS and aiming to understand the microscopic processes occurring at electrodes on the atomic level. A few of the exemplary keystone tools of EC-SS include EC-scanning probe microscopies, operando and in situ spectroscopies and electron microscopies, and differential EC mass spectrometry (DEMS). EC-SS indirectly (and often unconsciously) receives a great boost from the requirement for rational design of energy conversion and storage devices for the next generation of energetic landscapes. As a matter of fact, the number of material science groups deeply involved in such a challenging field has tremendously expanded and, within such a panorama, EC and SS investigations are intimately combined in a huge number of papers. The aim of this Special Issue is to offer an open access forum where researchers in the field of electrochemistry, surface science, and materials science could outline the great advances that can be reached by exploiting EC-SS approaches. Papers addressing both the basic science and more applied issues in the field of EC-SS and energy conversion and storage materials have been published in this Special Issue.
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Keywords
- Adhesion
- adsorbed OH
- AES
- alkanthiols
- alkoxyamine surfaces
- ammonia activation
- APTES
- Au
- Au nanocrystals
- Auger-Electron Spectroscopy
- Benchmarking
- bifunctional oxygen electrode
- bimetallic alloy
- Blackening of Steel
- carbon nanofiber
- carbon nanofibers (CNFs)
- catalysts
- cathode
- CdS
- click chemistry
- CO electro-oxidation
- CO oxidation
- cobalt oxide
- cobalt-based electrocatalyst
- combined non-covalent control
- Corrosion Protection
- Cu(111)
- cyclic voltammetry
- cyclic voltammetry (CV)
- d-band theory
- DFT
- diazonium salts
- direct methanol fuel cells
- DMFC
- ECALE
- EF-PEEM
- electro-oxidation
- electrocatalysis
- electrocatalysts
- electrochemical interface
- electrochemistry
- electrodeposited alloys
- electrodeposition
- electrophoretic deposition
- electrospinning
- electrosynthesis
- energy dispersive
- EPR spectroscopy
- EQCM
- FEXRAV
- flexible ITO
- formic acid oxidation
- Free electron laser
- Fuel cells
- gas diffusion electrode
- Gold
- Graphene
- graphitization
- hard X rays
- hydrogen adsorption
- hydroxyl radical
- In situ
- in situ ambient pressure XPS
- in situ EC-STM
- in-situ X-ray diffraction
- Iridium
- Lead OPD
- Magnetite
- mass transport
- mesopore
- metal-electrolyte interface
- methanol oxidation
- methanol oxidation reaction
- micropore
- model catalyst
- model systems
- n/a
- Nanoparticles
- near ambient pressure XPS
- Nickel
- nitrogen doping
- operando
- Ordered mesoporous carbon
- ordered mesoporous carbons
- ORR
- oxygen evolution reaction
- oxygen reduction
- Palladium
- PD
- Pd thin films
- PEMFC
- pH and concentration effects
- photo-electrochemistry
- Photochemistry
- photoconversion
- photoelectrochemistry
- photoelectron simulations
- Platinum
- platinum single crystals
- polymer
- polypyrrole
- porogen
- porous fiber
- porphyrins
- potential cycling
- potential stepping
- potential-dependent structures
- probe
- PT
- Pt single-crystal electrodes
- Pt–Ru catalysts
- pump &
- PVDF
- quick-XAS
- redox monolayers
- redox properties
- reduced graphene oxide
- SAMs
- scanning photoelectron microscopy
- self-assembly
- silicon nanoparticles
- silver single crystals
- SOFC
- Solid oxide fuel cells
- solid/liquid interface
- solvothermal method
- spin-coating
- surface alloy
- surface area
- Surface chemistry
- Surface modification
- surface nanostructures
- surface reconstruction
- Surface Science
- switchable surfaces
- thema EDItEUR::P Mathematics and Science::PN Chemistry
- thin-films
- TiO2
- underpotential deposition (upd)
- UPS
- water oxidation
- water splitting
- X-ray absorption spectroscopy
- XAFS
- XPS