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Organophosphorus chemistry is an important discipline within organic chemistry. Phosphorus compounds, such as phosphines, trialkyl phosphites, phosphine oxides (chalcogenides), phosphonates, phosphinates and >P(O)H species, etc., may be important starting materials or intermediates in syntheses. Let us mention the Wittig reaction and the related transformations, the Arbuzov- and the Pudovik reactions, the Kabachnik–Fields condensation, the Hirao reaction, the Mitsunobu reaction, etc. Other reactions, e.g., homogeneous catalytic transformations or C-C coupling reactions involve P-ligands in transition metal (Pt, Pd, etc.) complex catalysts. The synthesis of chiral organophosphorus compounds means a continuous challenge. Methods have been elaborated for the resolution of tertiary phosphine oxides and for stereoselective organophosphorus transformations. P-heterocyclic compounds, including aromatic and bridged derivatives, P-functionalized macrocycles, dendrimers and low coordinated P-fragments, are also of interest. An important segment of organophosphorus chemistry is the pool of biologically-active compounds that are searched and used as drugs, or as plant-protecting agents. The natural analogue of P-compounds may also be mentioned. Many new phosphine oxides, phosphinates, phosphonates and phosphoric esters have been described, which may find application on a broad scale. Phase transfer catalysis, ionic liquids and detergents also have connections to phosphorus chemistry. Green chemical aspects of organophosphorus chemistry (e.g., microwave-assisted syntheses, solvent-free accomplishments, optimizations, and atom-efficient syntheses) represent a dynamically developing field. Last, but not least, theoretical approaches and computational chemistry are also a strong sub-discipline within organophosphorus chemistry.
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Keywords
- 1
- 1,3-azaphospholes
- 1-(acylamino)alkylphosphonic acids
- 1-aminoalkylphosphonic acids
- 3-azaphospholes
- 31P NMR spectra of intermediates
- ?-amidoalkylating agents
- ?-hydroxyphosphonate
- alcoholysis
- allylic alkylation
- amino acids
- aminophosphonic acids
- asymmetric catalysis
- bis(phosphane) palladium complex
- C-H bond activation
- Chemistry
- chiral phosphines
- continuous flow reactor
- Copper
- cyclo-P5
- denufosol
- DFT
- DFT calculations
- dialkyl H-phosphonates
- Diels-Alder reaction
- dinucleotides
- diphosphines
- diquafosol
- dissociation constants
- dry eye syndrome
- dynamic and specific NMR parameters
- electronic parameters
- electrophilic substitution
- hydrolysis
- hydrolytic deacylation
- Mathematics & science
- mechanochemistry
- metallacycle
- Microwave
- Molybdenum
- N-acylimine
- N-acyliminium cation
- NMR-controlled titration
- NORPHOS
- O-derivatization
- organophosphorus chemistry
- oxidation
- phosphonic acids
- phosphonium salts
- phosphonocarboxylic acids
- Phosphorylation
- polycyclic compounds
- Pudovik reaction
- QTAIM
- rearrangement
- Silver
- stability constants
- stereoselective synthesis
- Substitution
- synergy
- transesterification
- triple-decker
- weakly coordinating
Links
DOI: 10.3390/books978-3-03928-237-1Editions
