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Porphyrin-Based Compounds: Synthesis and Application
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Porphyrins, metalloporphyrins, and their analogs are a family of macrocycles that are ubiquitous in nature, playing key roles in a myriad of biological functions, such as in plant light-harvesting (e.g., chlorophyll, a magnesium–chlorin complex), oxygen binding and transport (e.g., heme group, an iron–porphyrin complex, responsible for animal cellular respiration), and bacteria photosynthesis. The pivotal functions fulfilled by these naturally occurring porphyrinoids have motivated and inspired organic chemists to produce synthetic porphyrins and analogs in the laboratory. In recent years, a multitude of applications for porphyrins has shifted the focus from purely academic interest to industrial processes. There is a growing recognition of the need to develop new, more selective, and environmentally friendly synthetic methods. Within this Special Issue, readers will find a collection of 16 original research papers and a comprehensive review, all dedicated to exploring the synthesis and functionalization of tetrapyrrolic macrocycles. These papers shed light on the vast potential applications of these compounds across various fields.
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Keywords
- antimicrobial resistance
- array
- artificial photosynthesis
- asymmetric catalysis
- asymmetrical porphyrins
- BODIPY
- building block
- C-H functionalization
- carboxylated pyrrolidine-fused chlorin
- chemical-biological interactions
- Chemistry
- chiral layers
- Chirality
- chloro
- chlorophyll a derivatives
- circular dichroism
- copper-64
- copper-free Sonogashira coupling
- corroles
- density functionals
- DFT
- Diels–Alder reaction
- ENDOR
- epoxidation
- EPR spectroscopy
- ethyne
- fluorescence
- gas sensors
- glutathione detection
- gram-positive bacteria
- Green chemistry
- human serum albumin
- human U937 monocytic cells
- HYSCORE
- imidazolidin-4-ones
- iron porphyrin
- Mathematics & science
- membrane anisotropy
- methyl ester
- molecular docking
- MRSA
- n/a
- nitro
- Organic Chemistry
- organocatalysis
- organometallic
- oxidation catalysis
- perylene
- phenothiazine
- Photobiology
- photocatalysis
- photodynamic inactivation
- photodynamic therapy
- photophysics
- photosensitizer
- photosensitizers
- phthalocyanines
- porphyrin
- porphyrin macrocycles
- porphyrinoids
- porphyrins
- positron emission tomography
- potassium iodide
- pyridyl
- quartz microbalances
- radical cation
- reductive amination
- Reference, information & interdisciplinary subjects
- reflectance anisotropy spectroscopy
- renewable aromatics
- Research & information: general
- sarco/endoplasmic reticulum Ca2+-ATPase (SERCA2b)
- semisynthesis
- singlet oxygen
- slo1
- solar
- solubility
- spectroelectrochemistry
- spectroscopy
- Spirulina maxima
- Staphylococcus aureus
- sulfonamides
- supramolecular chirality
- SUR2
- thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GP Research and information: general
- thema EDItEUR::P Mathematics and Science::PN Chemistry
- thema EDItEUR::P Mathematics and Science::PN Chemistry::PNN Organic chemistry
- theranostic agents
- trans-A2B-corroles
- transition metals
- transmembrane potential
Links
DOI: 10.3390/books978-3-0365-9401-9Editions