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Solvatochromic Probes and Their Applications in Molecular Interaction Studies—a Themed Issue to Honor Professor Dr. Christian Reichardt
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Solvent polarity and hydrogen-bonding character play important roles in determining the magnitude of the solute-solvent interactions that control chemical reaction rates and equilibrium concentrations of chemically special species dissolved in both water and organic mono-solvents, as well as in binary (and higher-order multicomponent) solvent systems and molecularly organized aqueous-surfactant mixtures. Spectroscopic methods employing solvatochromic probe molecules have provided valuable information in the form of empirical solvent polarity and hydrogen-bonding scales that can be used to understand and predict the effect of binary solvent composition on solute solubility, equilibrium constants, and chemical reaction rates, to investigate preferential solvation in binary solvent mixtures, and to examine interfacial regions of aqueous micelles formed by ionic surfactants.This Special Issue contains five very informative review articles as well as ten original research papers and communications that report the synthesis of new solvatochromic probe molecules, measurement of new spectroscopic data, and development of new computational methods. The large range of topics covered illustrates that solvatochromic probe studies have been and still continue to be a very important and active research area. This Special Issue will be a valuable resource for researchers conducting solvatochromic probe studies.
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Keywords
- Abraham model
- acid–base indicators
- apparent dissociation constants
- average molar concentration
- binary mixtures
- binary solvent mixtures
- biopolymer dissolution
- Catalan SPP
- compatibility
- computational chemistry
- condensed phases
- cycloimmonium ylids
- deep eutectic solvent
- DFT
- electrical surface potential
- ester hydrolysis
- ET(30)
- ET(30) scale
- ET(30) solvent polarity parameter
- excited-state dipole moment
- fluorescence
- Glyceline
- Green chemistry
- hydration
- hydrogen bonding
- hydrogen-bonds
- ionic liquids
- Kamlet—Taft parameters
- KAT
- Lithium chloride
- Molecular Dynamics
- molecular dynamics modeling
- nature and strength of molecular interactions
- Nile Red dye
- on the polarizability of diphenylpolyenes in Cl4C and in Cl2CH2
- paracetamol
- pharmaceuticals
- physicochemical properties of aqueous solutions
- Plasticizers
- polarity
- polarizability
- predictive modeling
- protic ionic liquids
- pyrene
- refractive index
- Reichardt indicator
- Reichardt polarity
- Reichardts dye
- Reichardt’s betaine dye 33
- Reichardt’s dye
- Reichardt’s dye ET(30)
- Reichardt’s dye ET(33)
- rubbers
- solubility
- solubility parameter
- solubility prediction
- solvation
- solvation models
- solvatochromic dyes
- solvatochromic probes
- solvatochromic Reichardt’s dyes
- solvatochromic study
- solvatochromism
- solvatochromism of diphenylpolyenes
- solvent composition
- solvent effect on the spectra of organic compounds
- solvent mixtures
- solvent parameters
- solvent polarity scales
- solvent properties
- solvent structure
- solvent substitution
- surfactant micelles
- thema EDItEUR::P Mathematics and Science
- thema EDItEUR::P Mathematics and Science::PN Chemistry
- thema EDItEUR::P Mathematics and Science::PN Chemistry::PNR Physical chemistry
- Water
Links
DOI: 10.3390/books978-3-7258-1037-6Editions